Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Taylor, R.
Title:   The mechanism of thermal eliminations. Part 28 [1]: thermal decomposition of benzoylformic acid
Journal:   Int. J. Chem. Kinet.
Volume:   23
Page(s):   247 - 250
Year:   1991
Reference type:   Journal article
Squib:   1991TAY247-250

Reaction:   Benzeneacetic acid, α-oxo-Benzaldehyde + CO2
Reaction order:   1
Temperature:   543 - 584 K
Rate expression:   5.75x1014 [s-1] e-174603912 [J/mole]/RT
Bath gas:   Benzeneacetic acid, α-oxo-
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
543
550
575
584