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Accessibility information
Author(s):   Atkinson, R.; Baulch, D.L.; Cox, R.A.;Hampson Jr., R.F.; Kerr, J.A.; Troe, J.
Title:   Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry. Supplement IV, IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry
Journal:   J. Phys. Chem. Ref. Data
Volume:   21
Supplement:   4
Page(s):   1125 - 1568
Year:   1992
Reference type:   Journal article
Squib:   1992ATK/BAU1125-1568

Reaction:   CH3OH + NO3 → Products
Reaction order:   2
Temperature:   290 - 480 K
Rate expression:   1.3x10-12 [cm3/molecule s] e-21285 [±5745 J/mole]/RT
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
290 1.91E-16
300 2.56E-16
325 4.93E-16
350 8.66E-16
375 1.41E-15
400 2.16E-15
425 3.15E-15
450 4.40E-15
475 5.93E-15
480 6.28E-15