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Title: Time resolved kinetic studies of the gas-phase reactions of dimethylsilylene with some O-donor molecules: Part I. Room temperature studies
Journal: Int. J. Chem. Kinet.
Volume: 24
Page(s): 127 - 143
Year: 1992
Reference type: Journal article
Squib: 1992BAG/BLI127-143
Reaction:
Oxirane + (CH3)2Si → C2H4 + (CH3)2Si=O
Reaction order:
2
Temperature:
295
K
Pressure: 1.33E-3 - 1.33E-2 bar
Rate expression:
3.89x10-12 [±7.47x10-13 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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