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Accessibility information
Author(s):   Buravtsev, N.N.; Grigorev, A.S.; Zaidman, O.A.; Kolbanovskii, Y.A.; Markelov, M.Y.; Sadogurskii, M.N.; Treger, Y.A.
Title:   Dehydrochlorination of chloralkanes under the strictly homogeneous conditions. 1. Kinetics of high-temperature decay of 1,2-dichloroethane under adiabatic compression
Journal:   Khim. Fiz.
Volume:   11
Page(s):   210 - 217
Year:   1992
Reference type:   Journal article
Squib:   1992BUR/GRI210-217

Reaction:   CH2ClCH2ClCH2=CHCl + HCl
Reaction order:   1
Temperature:   920 - 1050 K
Pressure:  1.01 bar
Rate expression:   1.26x1016 [s-1] e-271883 [±8314472 J/mole]/RT
Uncertainty:   1.58
Bath gas:   CH2ClCH2Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
920 4.61E0
925 5.59E0
950 1.42E1
975 3.43E1
1000 7.92E1
1025 1.76E2
1050 3.76E2