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Accessibility information
Author(s):   DeMore, W.B.
Title:   Relative rate constants for the reactions of OH with methane and methyl chloroform
Journal:   Geophys. Res. Lett.
Volume:   19
Page(s):   1367 - 1370
Year:   1992
Reference type:   Journal article
Squib:   1992DEM1367-1370

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Reference reaction:   CH4 + ·OH·CH3 + H2O
Reference reaction order:   2
Temperature:   277 - 356 K
Pressure:  1.01 bar
Rate expression:   6.19x10-1 e2420 [J/mole]/RT
Uncertainty:   1.0700001
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
277 1.77E0
300 1.63E0
325 1.52E0
350 1.42E0
356 1.40E0