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Title: Chlorine initiated photooxidation studies of hydrochlorofluorocarbons (HCFCs) and hydrofluorocarbons (HFCs): results for HCFC-22 (CHClF2); HFC-41 (CH3F); HCFC-124 (CClFHCF3); HFC-125 (CF3CHF2); HFC-134a (CF3CH2F); HCFC-142b (CClF2CH3); and HFC-152a (CHF2CH3)
Journal: Int. J. Chem. Kinet.
Volume: 24
Page(s): 1067 - 1081
Year: 1992
Reference type: Journal article
Squib: 1992EDN/DRI1067-1081
Reaction:
C2F5H + Cl → C2F5 + HCl
Reaction order:
2
Reference reaction:
HFCO + Cl → FCO + HCl
Reference reaction order:
2
Temperature:
295
K
Pressure: 0.93 bar
Rate expression:
2.2x10-1±1.1x10-2
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
View full bibliographic record.