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Author(s):   Ortiz de Zarate, A.; Martinex, R.; Sanchez Rayo, M.N.; Castano, F.; Hancock, G.
Title:   Preparation of CHF (X 1A') by infrared multiphoton dissociation and reactions with alkenes
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   88
Page(s):   535 - 541
Year:   1992
Reference type:   Journal article
Squib:   1992ORT/MAR535-541

Reaction:   1,3-Butadiene + ·CHF → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-3 - 6.67E-3 bar
Rate expression:   2.19x10-11 [±3.16x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

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