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Title: Direct measurement of the reaction CH3 + OH and its pathways between 300 and 480 K
Journal: Symp. Int. Combust. Proc.
Volume: 24
Page(s): 597 - 604
Year: 1992
Reference type: Journal article
Squib: 1992OSE/STO597-604
Reaction:
·CH3 + ·OH → CH3OH
Reaction order:
3
Temperature:
300 - 480
K
Pressure: 3.07E-4 - 9.00E-3 bar
Rate expression:
6.4x10-29 [cm6/molecule2 s] e8564 [J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm6/molecule2 s] |
|---|---|
| 300 | 1.98E-27 |
| 325 | 1.52E-27 |
| 350 | 1.21E-27 |
| 375 | 9.97E-28 |
| 400 | 8.40E-28 |
| 425 | 7.22E-28 |
| 450 | 6.31E-28 |
| 475 | 5.59E-28 |
| 480 | 5.47E-28 |