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Title: Kinetics of the OH reaciton with methyl chloroform and its atmospheric implications
Journal: Science
Volume: 257
Page(s): 227 - 230
Year: 1992
Reference type: Journal article
Squib: 1992TAL/MEL227-230
Reaction:
CH3CCl3 + ·OH → H2O + CCl3CH2
Reaction order:
2
Temperature:
243 - 379
K
Pressure: 3.33E-2 - 1.00E-1 bar
Rate expression:
1.74x10-12 [±3.32x10-13 cm3/molecule s] e-12887 [±515 J/mole]/RT
Uncertainty:
1.08
Bath gas:
CH3CCl3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 243 | 2.96E-15 |
| 250 | 3.54E-15 |
| 275 | 6.22E-15 |
| 300 | 9.94E-15 |
| 325 | 1.48E-14 |
| 350 | 2.08E-14 |
| 375 | 2.79E-14 |
| 379 | 2.92E-14 |