Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Laser photolysis/laser-induced fluorescence studies of the reaction of hydroxyl with 1,1,2-trichloroethane over an extended temperature range
Journal: J. Phys. Chem.
Volume: 96
Page(s): 1293 - 1296
Year: 1992
Reference type: Journal article
Squib: 1992TAY/JIA1293-1296
Reaction:
CH2=CCl2 + ·OH → Products
Reaction order:
2
Temperature:
600 - 800
K
Pressure: 0.99 bar
Rate expression:
2.51x10-11 [cm3/molecule s] e-25193 [J/mole]/RT
Bath gas:
He
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 600 | 1.61E-13 |
| 625 | 1.97E-13 |
| 650 | 2.37E-13 |
| 675 | 2.82E-13 |
| 700 | 3.31E-13 |
| 725 | 3.84E-13 |
| 750 | 4.41E-13 |
| 775 | 5.03E-13 |
| 800 | 5.68E-13 |