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Author(s):   Taylor, P.H.; Jiang, Z.; Dellinger, B.
Title:   Laser photolysis/laser-induced fluorescence studies of the reaction of hydroxyl with 1,1,2-trichloroethane over an extended temperature range
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   1293 - 1296
Year:   1992
Reference type:   Journal article
Squib:   1992TAY/JIA1293-1296

Reaction:   CH2=CCl2 + ·OH → Products
Reaction order:   2
Temperature:   600 - 800 K
Pressure:  0.99 bar
Rate expression:   2.51x10-11 [cm3/molecule s] e-25193 [J/mole]/RT
Bath gas:   He
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
600 1.61E-13
625 1.97E-13
650 2.37E-13
675 2.82E-13
700 3.31E-13
725 3.84E-13
750 4.41E-13
775 5.03E-13
800 5.68E-13