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Accessibility information
Author(s):   Tsang, W.; Herron, J.T.
Title:   Kinetics and thermodynamics of the reaction SF6 = SF5 + F
Journal:   J. Chem. Phys.
Volume:   96
Page(s):   4272 - 4282
Year:   1992
Reference type:   Journal article
Squib:   1992TSA/HER4272-4282

Reaction:   SF6SF5 + ·F
Reaction order:   1
Temperature:   1700 - 2000 K
Rate expression:   3.38x1017 [s-1] (T/298 K)-1.90 e-422375 [J/mole]/RT
Bath gas:   Ar
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1700 1.30E3
1725 1.95E3
1750 2.89E3
1775 4.24E3
1800 6.14E3
1825 8.80E3
1850 1.25E4
1875 1.76E4
1900 2.45E4
1925 3.38E4
1950 4.62E4
1975 6.28E4
2000 8.45E4