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Accessibility information
Author(s):   Chiorboli, C.; Piazza, R.; Tosato, M.L.; Carassiti, V.
Title:   Atmospheric chemistry: rate constants of the gas-phase reactions between haloalkanes of environmental interest and hydroxyl radicals
Journal:   Coord. Chem. Rev.
Volume:   125
Page(s):   241 - 250
Year:   1993
Reference type:   Journal article
Squib:   1993CHI/PIA241-250

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993CHI/PIA241-250   CHCl3 + ·OH·CCl3 + H2O  298   8.32E-14           8.32E-14  2
  1993CHI/PIA241-250   CH3CCl3 + ·OHH2O + CCl3CH2  298   1.69E-14           1.69E-14  2
  1993CHI/PIA241-250   CH3Br + ·OHH2O + ·CH2Br  298   4.90E-14           4.90E-14  2
  1993CHI/PIA241-250   CH3Cl + ·OH·CH2Cl + H2O  298   6.03E-14           6.03E-14  2
  1993CHI/PIA241-250   CH2Br2 + ·OHH2O + CHBr2  298   3.89E-14           3.89E-14  2
  1993CHI/PIA241-250   C2H5Br + ·OH → Other Products + H2O  298   3.64E-13           3.64E-13  2
  1993CHI/PIA241-250   CH2ClBr + ·OHH2O + ·CHBrCl  298   4.68E-14           4.68E-14  2
  1993CHI/PIA241-250   C2H5Cl + ·OH → Other Products + H2O  298   4.37E-13           4.37E-13  2
  1993CHI/PIA241-250   CH2Cl2 + ·OHCHCl2 + H2O  298   5.63E-14           5.63E-14  2
  1993CHI/PIA241-250   CH2F2 + ·OH·CHF2 + H2O  298   9.78E-15           9.78E-15  2
  1993CHI/PIA241-250   CHBr3 + ·OHCBr3 + H2O  298   4.68E-14           4.68E-14  2
  1993CHI/PIA241-250   CHBrCl2 + ·OHH2O + BrCCl2  298   6.92E-14           6.92E-14  2
  1993CHI/PIA241-250   CH3CHCl2 + ·OH → Other Products + H2O  298   4.17E-13           4.17E-13  2
  1993CHI/PIA241-250   CH3CHF2 + ·OH → Other Products + H2O  298   7.09E-14           7.09E-14  2
  1993CHI/PIA241-250   CHFCl2 + ·OH·CCl2F + H2O  298   3.39E-14           3.39E-14  2
  1993CHI/PIA241-250   CHF2Cl + ·OH·CClF2 + H2O  298   1.41E-14           1.41E-14  2
  1993CHI/PIA241-250   CHF3 + ·OH·CF3 + H2O  298   5.89E-15           5.89E-15  2
  1993CHI/PIA241-250   CH3CF2Cl + ·OH → CF2ClCH2· + H2O  298   2.87E-15           2.87E-15  2
  1993CHI/PIA241-250   1,2-Dibromo-1,1-dichloroethane + ·OH → CCl2BrCHBr· + H2O  298   1.41E-13           1.41E-13  2
  1993CHI/PIA241-250   CF2BrCH2Br + ·OH → CF2BrCHBr + H2O  298   2.46E-14           2.46E-14  2
  1993CHI/PIA241-250   CF3CH2Cl + ·OHH2O + CF3CHCl  298   1.45E-14           1.45E-14  2
  1993CHI/PIA241-250   Pentabromoethane + ·OH → CBr3CBr2· + H2O  298   1.17E-13           1.17E-13  2
  1993CHI/PIA241-250   CHCl2CCl3 + ·OH → C2Cl5 + H2O  298   3.02E-13           3.02E-13  2
  1993CHI/PIA241-250   CHBr2CH2Br + ·OH → Other Products + H2O  298   1.48E-13           1.48E-13  2
  1993CHI/PIA241-250   CHCl2CH2Cl + ·OH → Other Products + H2O  298   2.57E-13           2.57E-13  2
  1993CHI/PIA241-250   Ethane, 1,1,2,2-tetrabromo- + ·OH → Other Products + H2O  298   1.17E-13           1.17E-13  2
  1993CHI/PIA241-250   (CHCl2)2 + ·OHH2O + CHCl2C(·)Cl2  298   2.46E-13           2.46E-13  2
  1993CHI/PIA241-250   CH2BrCH2Br + ·OH → CH2BrCH(·)Br + H2O  298   1.86E-13           1.86E-13  2
  1993CHI/PIA241-250   CH2BrCH2Cl + ·OH → Other Products + H2O  298   2.24E-13           2.24E-13  2
  1993CHI/PIA241-250   CH2ClCH2Cl + ·OHH2O + CH2ClCHCl·  298   2.69E-13           2.69E-13  2
  1993CHI/PIA241-250   CHClBr2 + ·OHH2O + CClBr2  298   5.75E-14           5.75E-14  2
  1993CHI/PIA241-250   CF3CHClBr + ·OHH2O + CF3CClBr  298   1.78E-14           1.78E-14  2
  1993CHI/PIA241-250   CF3CHCl2 + ·OHH2O + CF3CCl2  298   2.14E-14           2.14E-14  2
  1993CHI/PIA241-250   CH2FCHFCl + ·OH → Other Products + H2O  298   4.47E-14           4.47E-14  2
  1993CHI/PIA241-250   CH2ClCHF2 + ·OH → Other Products + H2O  298   4.47E-14           4.47E-14  2
  1993CHI/PIA241-250   C2H5F + ·OH → Other Products + H2O  298   1.78E-13           1.78E-13  2
  1993CHI/PIA241-250   1,2-Dibromo-1,1,2-trifluoroethane + ·OH → CF2BrCFBr· + H2O  298   1.48E-14           1.48E-14  2
  1993CHI/PIA241-250   CF2BrCHFCl + ·OH → CF2BrCFCl· + H2O  298   1.78E-14           1.78E-14  2
  1993CHI/PIA241-250   Ethane, 1,1,1,2-tetrachloro-2-fluoro- + ·OH → CCl3CFCl· + H2O  298   1.23E-13           1.23E-13  2
  1993CHI/PIA241-250   CCl3CHF2 + ·OH → CCl3CF2· + H2O  298   5.13E-14           5.13E-14  2
  1993CHI/PIA241-250   Ethane, 1,1,2,2-tetrachloro-1-fluoro- + ·OH → ·CCl2CFCl2 + H2O  298   1.23E-13           1.23E-13  2
  1993CHI/PIA241-250   CCl2FCHClF + ·OHH2O + CFCl2CFCl  298   5.13E-14           5.13E-14  2
  1993CHI/PIA241-250   CF2ClCHFCl + ·OHH2O + ·CFClCF2Cl  298   2.14E-14           2.14E-14  2
  1993CHI/PIA241-250   Ethane, 1-chloro-1,1,2,2-tetrafluoro- + ·OH → ·CF2CF2Cl + H2O  298   8.72E-15           8.72E-15  2
  1993CHI/PIA241-250   C2F5H + ·OHC2F5 + H2O  298   3.64E-15           3.64E-15  2
  1993CHI/PIA241-250   CHBr2CHF2 + ·OH → Other Products + H2O  298   2.87E-14           2.87E-14  2
  1993CHI/PIA241-250   Ethane, 1,1,2-trichloro-2-fluoro- + ·OH → Other Products + H2O  298   1.02E-13           1.02E-13  2
  1993CHI/PIA241-250   CHF2CHF2 + ·OHH2O + CHF2CF2  298   7.26E-15           7.26E-15  2
  1993CHI/PIA241-250   CH3CF3 + ·OHCF3CH2 + H2O  298   1.20E-15           1.20E-15  2
  1993CHI/PIA241-250   CH2FCF2Cl + ·OH → ·CHFCF2Cl + H2O  298   1.45E-14           1.45E-14  2
  1993CHI/PIA241-250   CF3CBrH2 + ·OH → CF3CHBr· + H2O  298   1.20E-14           1.20E-14  2
  1993CHI/PIA241-250   CH2FCHCl2 + ·OH → Other Products + H2O  298   1.07E-13           1.07E-13  2
  1993CHI/PIA241-250   Ethane, 1,2-dichloro-1-fluoro- + ·OH → Other Products + H2O  298   1.07E-13           1.07E-13  2
  1993CHI/PIA241-250   CH2FCHF2 + ·OH → Other Products + H2O  298   1.83E-14           1.83E-14  2
  1993CHI/PIA241-250   1,2-Dichloro-1,2-difluoroethane + ·OH → ·CFClCHFCl + H2O  298   4.27E-14           4.27E-14  2
  1993CHI/PIA241-250   CHF2CHFCl + ·OH → Other Products + H2O  298   1.74E-14           1.74E-14  2
  1993CHI/PIA241-250   Ethane, 1,1-dichloro-2,2-difluoro- + ·OH → Other Products + H2O  298   4.27E-14           4.27E-14  2
  1993CHI/PIA241-250   CH3CHBr2 + ·OH → Other Products + H2O  298   2.82E-13           2.82E-13  2
  1993CHI/PIA241-250   CH3F + ·OH·CH2F + H2O  298   2.46E-14           2.46E-14  2
  1993CHI/PIA241-250   CH2FCl + ·OHH2O + ·CClFH  298   2.34E-14           2.34E-14  2
  1993CHI/PIA241-250   CH2FCH2F + ·OHH2O + CH2FCHF  298   4.68E-14           4.68E-14  2
  1993CHI/PIA241-250   1,1,1,2-Tetrabromoethane + ·OH → CBr3CHBr· + H2O  298   9.78E-14           9.78E-14  2
  1993CHI/PIA241-250   CH2ClCCl3 + ·OHH2O + CCl3CHCl  298   2.04E-13           2.04E-13  2
  1993CHI/PIA241-250   CH2FCH2Br + ·OH → Other Products + H2O  298   9.33E-14           9.33E-14  2
  1993CHI/PIA241-250   Ethane, 1-chloro-2-fluoro- + ·OH → Other Products + H2O  298   1.12E-13           1.12E-13  2
  1993CHI/PIA241-250   CH2ClCFCl2 + ·OH → ·CHClCFCl2 + H2O  298   8.52E-14           8.52E-14  2
  1993CHI/PIA241-250   CF3CH2F + ·OHH2O + CF3CHF  298   6.03E-15           6.03E-15  2
  1993CHI/PIA241-250   CHF2CFCl2 + ·OH → ·CF2CFCl2 + H2O  298   2.14E-14           2.14E-14  2
  1993CHI/PIA241-250   CHBrF2 + ·OHH2O + CBrF2  298   1.17E-14           1.17E-14  2
  1993CHI/PIA241-250   Ethane, 1-chloro-1-fluoro- + ·OH → Other Products + H2O  298   1.69E-13           1.69E-13  2
  1993CHI/PIA241-250   CF2ClCH2Cl + ·OH → ·CHClCClF2 + H2O  298   3.55E-14           3.55E-14  2
  1993CHI/PIA241-250   CH2FCFCl2 + ·OH → ·CHFCFCl2 + H2O  298   3.55E-14           3.55E-14  2
  1993CHI/PIA241-250   CCl3CH2F + ·OH → ·CHF-CCl3 + H2O  298   8.52E-14           8.52E-14  2
  1993CHI/PIA241-250   CF3CHFCl + ·OH → CF3CFCl· + H2O  298   8.72E-15           8.72E-15  2
  1993CHI/PIA241-250   ·OH + CH3CCl2F → ·CH2CCl2F + H2O  298   6.92E-15           6.92E-15  2

Search returned 75 records.