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Title: Kinetics and mechanism of the thermal gas-phase reaction between trifluoromethylhypofluorite, CF3OF, and trichloroethene
Journal: J. Chem. Soc. Faraday Trans.
Volume: 89
Page(s): 451 - 455
Year: 1993
Reference type: Journal article
Squib: 1993CZA/CZA451-455
Reaction:
C2HCl3 + CF3OF → Other Products + CF3O
Reaction order:
2
Temperature:
284 - 324
K
Pressure: 9.33E-3 - 7.71E-2 bar
Rate expression:
5.48x10-15 [±3.32x10-15 cm3/molecule s] e-47309 [±9894 J/mole]/RT
Bath gas:
CF3OF
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 284 | 1.09E-23 |
| 300 | 3.17E-23 |
| 324 | 1.29E-22 |