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Accessibility information
Author(s):   Donaghy, T.; Shanahan, I.; Hande, M.; Fitzpatrick, S.
Title:   Rate constants and atmospheric lifetimes for the reactions of OH radicals and Cl atoms with haloalkanes
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   273 - 284
Year:   1993
Reference type:   Journal article
Squib:   1993DON/SHA273-284

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993DON/SHA273-284   C2H5Br + ·OH → Other Products + H2O  300   0.88              2
  Reference reaction:  C2H6 + ·OH → ·C2H5 + H2O 2
  1993DON/SHA273-284   C2H5Br + Cl → Other Products + HCl  300   0.24              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   iso-C3H7Br + ·OH → Other Products + H2O  298   0.12           0.12  2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   iso-C3H7Br + Cl → Other Products + HCl  298   0.48           0.48  2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   iso-C3H7Cl + ·OH → Other Products + H2O  303   0.12              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   iso-C3H7Cl + Cl → Other Products + HCl  303   0.36              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   n-C3H7Br + ·OH → Other Products + H2O  300   0.16              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   n-C3H7Br + Cl → Other Products + HCl  300   1.07              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   n-C4H9Br + ·OH → Other Products + H2O  299   0.33              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   n-C4H9Br + Cl → Other Products + HCl  299   2.46              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   n-C5H11Br + ·OH → Other Products + H2O  304   0.52              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   n-C5H11Br + Cl → Other Products + HCl  299   3.76              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   Hexane, 1-bromo- + ·OH → Other Products + H2O  306   0.76              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   Hexane, 1-bromo- + Cl → Other Products + HCl  306   4.76              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   CH2ClCH2CH2Cl + ·OH → Other Products + H2O  305   0.10              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   tert-C4H9Cl + ·OH → H2O + (CH3)2CClCH2  298   0.06           0.06  2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   CH2ClCH2CH2Cl + Cl → Other Products + HCl  305   0.19              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   tert-C4H9Cl + Cl → HCl + (CH3)2CClCH2  298   0.23           0.23  2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   n-C3H7Cl + ·OH → Other Products + H2O  303   0.15              2
  Reference reaction:  Cyclohexane + ·OH → Cyclohexyl + H2O 2
  1993DON/SHA273-284   n-C3H7Cl + Cl → Other Products + HCl  303   0.85              2
  Reference reaction:  C2H6 + Cl → ·C2H5 + HCl 2
  1993DON/SHA273-284   C2H5Br + ·OH → Other Products + H2O  300   2.51E-13              2
  1993DON/SHA273-284   C2H5Br + Cl → Other Products + HCl  300   1.40E-11              2
  1993DON/SHA273-284   iso-C3H7Br + ·OH → Other Products + H2O  298   8.80E-13           8.80E-13  2
  1993DON/SHA273-284   iso-C3H7Br + Cl → Other Products + HCl  298   2.71E-11           2.71E-11  2
  1993DON/SHA273-284   iso-C3H7Cl + ·OH → Other Products + H2O  303   9.22E-13              2
  1993DON/SHA273-284   iso-C3H7Cl + Cl → Other Products + HCl  303   2.01E-11              2
  1993DON/SHA273-284   n-C3H7Br + ·OH → Other Products + H2O  300   1.18E-12              2
  1993DON/SHA273-284   n-C3H7Br + Cl → Other Products + HCl  300   6.09E-11              2
  1993DON/SHA273-284   n-C4H9Br + ·OH → Other Products + H2O  299   2.46E-12              2
  1993DON/SHA273-284   n-C4H9Br + Cl → Other Products + HCl  299   1.40E-10              2
  1993DON/SHA273-284   n-C5H11Br + ·OH → Other Products + H2O  304   3.95E-12              2
  1993DON/SHA273-284   n-C5H11Br + Cl → Other Products + HCl  304   2.14E-10              2
  1993DON/SHA273-284   Hexane, 1-bromo- + ·OH → Other Products + H2O  306   5.85E-12              2
  1993DON/SHA273-284   Hexane, 1-bromo- + Cl → Other Products + HCl  306   2.72E-10              2
  1993DON/SHA273-284   n-C3H7Cl + ·OH → Other Products + H2O  303   1.12E-12              2
  1993DON/SHA273-284   tert-C4H9Cl + ·OH → H2O + (CH3)2CClCH2  298   4.10E-13           4.10E-13  2
  1993DON/SHA273-284   CH2ClCH2CH2Cl + ·OH → Other Products + H2O  305   7.80E-13              2
  1993DON/SHA273-284   tert-C4H9Cl + Cl → HCl + (CH3)2CClCH2  298   1.30E-11           1.30E-11  2
  1993DON/SHA273-284   n-C3H7Cl + Cl → Other Products + HCl  303   4.90E-11              2
  1993DON/SHA273-284   CH2ClCH2CH2Cl + Cl → Other Products + HCl  305   1.10E-11              2
Search returned 40 records.