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Title: Experimental and transition-state theory studies of the gas-phase reactions of AlCl with N2O, CO2, and SO2
Journal: J. Phys. Chem.
Volume: 97
Page(s): 7222 - 7227
Year: 1993
Reference type: Journal article
Squib: 1993FUT/FON7222-7227
Reaction:
CO2 + AlCl → Products
Reaction order:
2
Temperature:
900 - 1790
K
Pressure: 4.19E-2 - 0.11 bar
Rate expression:
1.16x10-15 [cm3/molecule s] (T/298 K)3.00 e-32426 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 900 | 4.21E-16 |
| 950 | 6.22E-16 |
| 1000 | 8.90E-16 |
| 1050 | 1.24E-15 |
| 1100 | 1.69E-15 |
| 1150 | 2.25E-15 |
| 1200 | 2.95E-15 |
| 1250 | 3.79E-15 |
| 1300 | 4.81E-15 |
| 1350 | 6.02E-15 |
| 1400 | 7.45E-15 |
| 1450 | 9.11E-15 |
| 1500 | 1.10E-14 |
| 1550 | 1.32E-14 |
| 1600 | 1.57E-14 |
| 1650 | 1.86E-14 |
| 1700 | 2.18E-14 |
| 1750 | 2.54E-14 |
| 1790 | 2.86E-14 |