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Accessibility information
Author(s):   Hidaka, Y.; Higashihara, T.; Ninomiya, N.; Oshita, H.; Kawano, H.
Title:   Thermal isomerization and decomposition of 2-butyne in shock waves
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   10977 - 10983
Year:   1993
Reference type:   Journal article
Squib:   1993HID/HIG10977-10983

Reaction:   1,3-ButadieneC2H4 + C2H2
Reaction order:   1
Temperature:   1100 - 1600 K
Rate expression:   1.0x1014 [s-1] e-313456 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 1.30E-1
1150 5.79E-1
1200 2.27E0
1250 7.97E0
1300 2.54E1
1350 7.45E1
1400 2.02E2
1450 5.11E2
1500 1.22E3
1550 2.73E3
1600 5.85E3