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Author(s):   Hidaka, Y.; Ninomiya, N.; Oshita, H.; Kawano, H.; Koike, T.
Title:   High temperature pyrolysis of 1,5-cyclooctadiene and 4-vinylcyclohexene in shock waves
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   1037 - 1042
Year:   1993
Reference type:   Journal article
Squib:   1993HID/NIN1037-1042

Reaction:   ·CH2CH=CHCH2CH2CH=CHCH2· → 1,3-Butadiene + 1,3-Butadiene
Reaction order:   1
Temperature:   880 - 1230 K
Pressure:  0.91 - 2.13 bar
Rate expression:   1.5x1014 [s-1] e-25110 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
880 4.85E12
900 5.23E12
925 5.73E12
950 6.24E12
975 6.77E12
1000 7.32E12
1025 7.88E12
1050 8.45E12
1075 9.04E12
1100 9.63E12
1125 1.02E13
1150 1.09E13
1175 1.15E13
1200 1.21E13
1225 1.27E13
1230 1.29E13