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Accessibility information
Author(s):   Kaiser, E.W.
Title:   Relative rate constants for reactions of HFC 152a, 143, 143a, 134a, and HCFC 124 with F or Cl atoms and for CF2CH3, CF2HCH2, and CF3CFH radicals with F2, Cl2, and O2
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   667 - 680
Year:   1993
Reference type:   Journal article
Squib:   1993KAI667-680

Reaction:   F2 + CF3CHF → C2F5H + ·F
Reaction order:   2
Reference reaction:   O2 + CF3CHF → CF3CFHO2·
Reference reaction order:   2
Temperature:   265 - 365 K
Pressure:  0.13 - 1.01 bar
Rate expression:   6.0x10-1±2.1x10-1 e-7150 [±1862 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
265 2.34E-2
275 2.63E-2
300 3.41E-2
325 4.26E-2
350 5.14E-2
365 5.69E-2