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Accessibility information
Author(s):   Michael, J.V.; Lim, K.P.; Kumaran, S.S.; Kiefer, J.H.
Title:   Thermal decomposition of carbon tetrachloride
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   1914 - 1919
Year:   1993
Reference type:   Journal article
Squib:   1993MIC/LIM1914-1919

Reaction:   CCl4·CCl3 + Cl
Reaction order:   1
Temperature:   1050 - 2200 K
Pressure:  0.25 - 0.97 bar
Rate expression:   7.19x1016 [s-1] (T/298 K)-2.29 e-288512 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 1.79E1
1100 7.21E1
1200 8.18E2
1300 6.30E3
1400 3.58E4
1500 1.59E5
1600 5.84E5
1700 1.82E6
1800 4.96E6
1900 1.21E7
2000 2.68E7
2100 5.48E7
2200 1.04E8