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Accessibility information
Author(s):   Doughty, A.; Bacskay, G.B.; Mackie, J.C.
Title:   Experimental and ab initio theoretical study of the kinetics of rearrangement of ketene imine to acetonitrile
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   13546 - 13555
Year:   1994
Reference type:   Journal article
Squib:   1994DOU/BAC13546-13555

Reaction:   CH2=C=NHCH3CN
Reaction order:   1
Temperature:   1300 - 1600 K
Pressure:  1.60E-3 - 2.00E-2 bar
Rate expression:   2.51x1013 [s-1] e-294332 [±14717 J/mole]/RT
Uncertainty:   3.1600001
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 3.75E1
1325 6.26E1
1350 1.03E2
1375 1.65E2
1400 2.62E2
1425 4.08E2
1450 6.26E2
1475 9.48E2
1500 1.41E3
1525 2.08E3
1550 3.03E3
1575 4.35E3
1600 6.18E3