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Accessibility information
Author(s):   Fagerstrom, K.; Lund, A.; Mahmoud, G.; Jodkowski, J.T.; Ratajczak, E.
Title:   Pressure and temperature dependence of the gas-phase reaction between methyl and hydroxyl radicals
Journal:   Chem. Phys. Lett.
Volume:   224
Page(s):   43 - 50
Year:   1994
Reference type:   Journal article
Squib:   1994FAG/LUN43-50

Reaction:   ·CH3 + ·OHCH3OH
Reaction order:   3
Temperature:   283 - 373 K
Pressure:  8.51E-2 - 1.00 bar
Rate expression:   2.48x10-27 [±6.62x10-28 cm6/molecule2 s] (T/298 K)-3.80
Bath gas:   SF6
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Ultrasonics
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
283 3.02E-27
300 2.42E-27
325 1.78E-27
350 1.35E-27
373 1.06E-27