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Accessibility information
Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants for the reactions of OH with CH3Cl, CH2Cl2, CHCl3, and CH3Br
Journal:   Geophys. Res. Lett.
Volume:   21
Page(s):   805 - 808
Year:   1994
Reference type:   Journal article
Squib:   1994HSU/DEM805-808

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994HSU/DEM805-808   CHCl3 + ·OH → ·CCl3 + H2O  283 - 357   1.20E-12       6485   8.76E-14  2
  1994HSU/DEM805-808   CHCl3 + ·OH → ·CCl3 + H2O  288 - 357   0.52       -4116   2.74  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1994HSU/DEM805-808   CH3Br + ·OH → H2O + ·CH2Br  298 - 360   4.40E-12       1.26E04   2.77E-14  2
  1994HSU/DEM805-808   CH3Br + ·OH → H2O + ·CH2Br  298 - 360   1.94       1929   0.89  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1994HSU/DEM805-808   CH3Cl + ·OH → ·CH2Cl + H2O  293 - 358   4.40E-12       1.22E04   3.17E-14  2
  1994HSU/DEM805-808   CH3Cl + ·OH → ·CH2Cl + H2O  293 - 358   1.91       1621   0.99  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1994HSU/DEM805-808   CH2Cl2 + ·OH → CHCl2 + H2O  293 - 360   2.19E-12       8156   8.15E-14  2
  1994HSU/DEM805-808   CH2Cl2 + ·OH → CHCl2 + H2O  293 - 360   0.97       -2444   2.60  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
Search returned 8 records.