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Accessibility information
Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants for the reactions of OH with CH3Cl, CH2Cl2, CHCl3, and CH3Br
Journal:   Geophys. Res. Lett.
Volume:   21
Page(s):   805 - 808
Year:   1994
Reference type:   Journal article
Squib:   1994HSU/DEM805-808

Reaction:   CHCl3 + ·OH·CCl3 + H2O
Reaction order:   2
Reference reaction:   CH3CHF2 + ·OH → Other Products + H2O
Reference reaction order:   2
Temperature:   288 - 357 K
Pressure:  1.01 bar
Rate expression:   5.2x10-1±1.1x10-1 e4116 [±535 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
288 2.90E0
300 2.71E0
325 2.38E0
350 2.14E0
357 2.08E0