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Accessibility information
Author(s):   Langer, S.; Ljungstrom, E.
Title:   Rates of reaction between the nitrate radical and some aliphatic ethers
Journal:   Int. J. Chem. Kinet.
Volume:   26
Page(s):   367 - 380
Year:   1994
Reference type:   Journal article
Squib:   1994LAN/LJU367-380

Reaction:   tert-C4H9OCH3 + NO3 → Products
Reaction order:   2
Reference reaction:   CH3CHO + NO3 → Products
Temperature:   258 - 373 K
Pressure:  6.67E-3 bar
Rate expression:   2.41x10-12 [±2.82x10-13 cm3/molecule s] e-20121 [±1613 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Electron beam
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
258 2.03E-16
275 3.63E-16
300 7.56E-16
325 1.41E-15
350 2.39E-15
373 3.66E-15