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Title: Rates of reaction between the nitrate radical and some aliphatic ethers
Journal: Int. J. Chem. Kinet.
Volume: 26
Page(s): 367 - 380
Year: 1994
Reference type: Journal article
Squib: 1994LAN/LJU367-380
Reaction:
tert-C4H9OCH3 + NO3 → Products
Reaction order:
2
Reference reaction:
CH3CHO + NO3 → Products
Temperature:
258 - 373
K
Pressure: 6.67E-3 bar
Rate expression:
2.41x10-12 [±2.82x10-13 cm3/molecule s] e-20121 [±1613 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Electron beam
Analytical technique:
Fourier transform (FTIR)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 258 | 2.03E-16 |
| 275 | 3.63E-16 |
| 300 | 7.56E-16 |
| 325 | 1.41E-15 |
| 350 | 2.39E-15 |
| 373 | 3.66E-15 |