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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Isomerization and decomposition of propylene oxide. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   1161 - 1170
Year:   1994
Reference type:   Journal article
Squib:   1994LIF/TAM1161-1170

Reaction:   Methyloxirane → Products
Reaction order:   1
Temperature:   835 - 1160 K
Pressure:  2.03 bar
Rate expression:   1.0x1014 [s-1] e-236131 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
835 1.69E-1
850 3.09E-1
875 8.02E-1
900 1.98E0
925 4.63E0
950 1.04E1
975 2.24E1
1000 4.63E1
1025 9.27E1
1050 1.79E2
1075 3.36E2
1100 6.13E2
1125 1.09E3
1150 1.88E3
1160 2.33E3