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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Isomerization and decomposition of propylene oxide. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   1161 - 1170
Year:   1994
Reference type:   Journal article
Squib:   1994LIF/TAM1161-1170

Reaction:   MethyloxiraneCH2=CHOCH3
Reaction order:   1
Temperature:   855 - 1110 K
Pressure:  2.03 bar
Rate expression:   1.62x1013 [s-1] e-246108 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
855 1.49E-2
875 3.30E-2
900 8.43E-2
925 2.05E-1
950 4.76E-1
975 1.06E0
1000 2.26E0
1025 4.66E0
1050 9.26E0
1075 1.78E1
1100 3.33E1
1110 4.25E1