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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Isomerization and decomposition of propylene oxide. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   1161 - 1170
Year:   1994
Reference type:   Journal article
Squib:   1994LIF/TAM1161-1170

Reaction:   MethyloxiraneC2H5CHO
Reaction order:   1
Temperature:   835 - 1160 K
Pressure:  2.03 bar
Rate expression:   1.82x1014 [s-1] e-244445 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
835 9.31E-2
850 1.73E-1
875 4.65E-1
900 1.18E0
925 2.86E0
950 6.60E0
975 1.46E1
1000 3.10E1
1025 6.36E1
1050 1.26E2
1075 2.41E2
1100 4.49E2
1125 8.14E2
1150 1.44E3
1160 1.79E3