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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Isomerization and decomposition of propylene oxide. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   1161 - 1170
Year:   1994
Reference type:   Journal article
Squib:   1994LIF/TAM1161-1170

Reaction:   Methyloxirane·CH3 + *CH2C(O)H
Reaction order:   1
Temperature:   835 - 1160 K
Pressure:  2.03 bar
Rate expression:   2.45x1013 [s-1] e-246108 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
835 9.86E-3
850 1.84E-2
875 4.98E-2
900 1.28E-1
925 3.10E-1
950 7.20E-1
975 1.60E0
1000 3.42E0
1025 7.04E0
1050 1.40E1
1075 2.70E1
1100 5.04E1
1125 9.17E1
1150 1.62E2
1160 2.03E2