Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   Thermal decomposition ofCH2Cl2
Journal:   Symp. Int. Combust. Proc.
Volume:   25
Page(s):   809 - 816
Year:   1994
Reference type:   Journal article
Squib:   1994LIM/MIC809-816

Reaction:   CH2Cl2·CHCl + HCl
Reaction order:   1
Temperature:   1400 - 2300 K
Pressure:  8.00E-3 - 2.13E-2 bar
Rate expression:   3.1x1014 [s-1] e-316781 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 4.70E2
1450 1.20E3
1500 2.89E3
1550 6.55E3
1600 1.41E4
1650 2.90E4
1700 5.73E4
1750 1.09E5
1800 1.99E5
1850 3.53E5
1900 6.06E5
1950 1.01E6
2000 1.65E6
2050 2.63E6
2100 4.09E6
2150 6.24E6
2200 9.34E6
2250 1.37E7
2300 1.98E7