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Title: Kinetics studies of the O(3P) + CH2Cl2 and CHCl3 reactions over the 468-1355 and 499-1090K
Journal: J. Phys. Chem.
Volume: 98
Page(s): 8411 - 8418
Year: 1994
Reference type: Journal article
Squib: 1994SU/LIM8411-8418
Reaction:
CHCl3 + O· → ·CCl3 + ·OH
Reaction order:
2
Temperature:
499 - 789
K
Pressure: 0.13 - 0.43 bar
Rate expression:
4.95x10-10 [cm3/molecule s] e-48972 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 499 | 3.70E-15 |
| 500 | 3.79E-15 |
| 525 | 6.64E-15 |
| 550 | 1.11E-14 |
| 575 | 1.76E-14 |
| 600 | 2.70E-14 |
| 625 | 4.00E-14 |
| 650 | 5.74E-14 |
| 675 | 8.03E-14 |
| 700 | 1.10E-13 |
| 725 | 1.47E-13 |
| 750 | 1.92E-13 |
| 775 | 2.48E-13 |
| 789 | 2.83E-13 |