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Title: Gas-phase kinetics of elimination reactions of pentane-2,4-dione derivatives
Journal: Int. J. Chem. Kinet.
Volume: 27
Page(s): 517 - 523
Year: 1995
Reference type: Journal article
Squib: 1995ALA/ELN517-523
Reaction:
CH3C(O)CH2C(O)OC2H5 → CH3COOC2H5 + H2C=C=O
Reaction order:
1
Temperature:
614 - 663
K
Rate expression:
5.0x1011 [s-1] e-141346 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 614 | 4.73E-1 |
| 625 | 7.69E-1 |
| 650 | 2.19E0 |
| 663 | 3.66E0 |