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Title: Kinetics and mechanism of the thermal gas-phase oxidation of trichloroethene by molecular oxygen in presence of trifluoromethylhypofluorite, CF3OF
Journal: Z. Phys. Chem. (Munich)
Volume: 191
Page(s): 103 - 118
Year: 1995
Reference type: Journal article
Squib: 1995CZA103-118
Reaction:
CHClFCCl2OO(.) + C2HCl3 → CHClFCCl2OOCHClCCl2(.)
Reaction order:
2
Temperature:
294 - 334
K
Pressure: 2.67E-2 - 0.81 bar
Rate expression:
1.56x10-12 [±1.33x10-12 cm3/molecule s] e-27022 [±11058 J/mole]/RT
Bath gas:
O2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 294 | 2.47E-17 |
| 300 | 3.08E-17 |
| 325 | 7.09E-17 |
| 334 | 9.28E-17 |