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Title: Reaction rate constants (295 K) for 3CH2 with H2S, SO2, and NO2: upper bounds for rate constants with less reactive partners
Journal: J. Phys. Chem.
Volume: 99
Page(s): 13467 - 13470
Year: 1995
Reference type: Journal article
Squib: 1995DAR/MOO13467-13470
Reaction:
(CH3)2CO + ·CH2 → Products
Reaction order:
2
Temperature:
295
K
Pressure: 3.37E-3 bar
Rate expression:
2.19x10-14 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:
H2C=C=O
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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