Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help

Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Temperature-dependent rate constants and substituent effects for the reactions of hydroxyl radicals with three partially fluorinated ethers
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   11141 - 11146
Year:   1995
Reference type:   Journal article
Squib:   1995HSU/DEM11141-11146

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995HSU/DEM11141-11146   CHF2-O-CHF2 + ·OH → CHF2OCF2· + H2O  298 - 368   1.91E-12       1.67E04   2.28E-15  2
  1995HSU/DEM11141-11146   CHF2-O-CHF2 + ·OH → CHF2OCF2· + H2O  298 - 368   1.05       3791   0.23  2
  Reference reaction:  CH3CCl3 + ·OH → H2O + CCl3CH2 2
  1995HSU/DEM11141-11146   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  301 - 370   1.55       1131      2
  Reference reaction:  CH2F2 + ·OH → ·CHF2 + H2O 2
  1995HSU/DEM11141-11146   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  298 - 381   1.93E-12       1.30E04   1.03E-14  2
  1995HSU/DEM11141-11146   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  298 - 381   0.65       1580   0.34  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM11141-11146   ·OH + Pentafluorodimethyl ether → H2O + CF3OCF2(·)  298 - 377   0.05       -890   0.08  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM11141-11146   ·OH + Pentafluorodimethyl ether → H2O + CF3OCF2(·)  298 - 393   4.70E-13       1.74E04   4.16E-16  2
  1995HSU/DEM11141-11146   ·OH + Pentafluorodimethyl ether → H2O + CF3OCF2(·)  298 - 393   0.74       -2153   1.76  2
  Reference reaction:  CHF3 + ·OH → ·CF3 + H2O 2
Search returned 8 records.