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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Isomerization and decomposition of 2,3-dimethyloxirane. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   10251 - 10260
Year:   1995
Reference type:   Journal article
Squib:   1995LIF/TAM10251-10260

Reaction:   cis-2,3-DimethyloxiraneC2H5COCH3
Reaction order:   1
Temperature:   900 - 1150 K
Rate expression:   6.03x1013 [s-1] e-235300 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.33E0
925 3.11E0
950 6.96E0
975 1.50E1
1000 3.09E1
1025 6.16E1
1050 1.19E2
1075 2.22E2
1100 4.05E2
1125 7.17E2
1150 1.24E3