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Title: Atmospheric chemistry of HFC-236fa: spectrokinetic investigation of the CF3CHO2.CF3 radical, its reaction with NO, and the fate of the CF3CHO.CF3 radical
Journal: J. Phys. Chem.
Volume: 99
Page(s): 5373 - 5378
Year: 1995
Reference type: Journal article
Squib: 1995MOG/PLA5373-5378
Reaction:
Propane, 1,1,1,3,3,3-hexafluoro- + Cl → HCl + (CF3)2CH·
Reaction order:
2
Reference reaction:
CD4 + Cl → CD3 + DCl
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
8.0x10-17 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Fourier transform (FTIR)
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