Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Rate constants for the reactions of fluorine atoms with alkanes and hydrofluorocarbons at room temperature
Journal: J. Chem. Soc. Faraday Trans.
Volume: 91
Page(s): 3041 - 3044
Year: 1995
Reference type: Journal article
Squib: 1995MOO/SMI3041-3044
Reaction:
C2F5H + ·F → C2F5 + HF
Reaction order:
2
Reference reaction:
CHF3 + ·F → ·CF3 + HF
Temperature:
298
K
Pressure: 0.80 bar
Rate expression:
3.65x10-13 [±3.99x10-14 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
View full bibliographic record.