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Title: Atmospheric chemistry of 1,1,1-trichloroethane: UV absorption spectra and self-reaction kinetics of CCl3CH2 and CCl3CH2O2 radicals, kinetics of the reactions of the CCl3CH2O2 radical with NO and NO2, and the fate of the alkoxy radical CCl3CH2O
Journal: J. Phys. Chem.
Volume: 99
Page(s): 6570 - 6579
Year: 1995
Reference type: Journal article
Squib: 1995PLA/NIE6570-6579
Reaction:
CH3CCl3 + ·F → HF + CCl3CH2
Reaction order:
2
Reference reaction:
O2 + ·F → O2F
Temperature:
295
K
Pressure: 0.97 bar
Rate expression:
6.79x10-12 [±1.49x10-12 cm3/molecule s]
Bath gas:
SF6
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Ultrasonics
Analytical technique:
Vis-UV absorption
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