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Accessibility information
Author(s):   Zachariah, M.R.; Tsang, W.
Title:   Theoretical calculation of thermochemistry, energetics, and kinetics of high-temperature SixHyOz reactions
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   5308 - 5318
Year:   1995
Reference type:   Journal article
Squib:   1995ZAC/TSA5308-5318

Reaction:   SiO2 + → (·)Si(O)OH
Reaction order:   2
Temperature:   1000 - 2500 K
Pressure:  1.01 bar
Rate expression:   1.79x10-9 [cm3/molecule s] (T/298 K)-4.00 e-23696 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1000 8.18E-13
1100 7.24E-13
1200 6.34E-13
1300 5.53E-13
1400 4.81E-13
1500 4.18E-13
1600 3.63E-13
1700 3.17E-13
1800 2.77E-13
1900 2.42E-13
2000 2.13E-13
2100 1.87E-13
2200 1.65E-13
2300 1.46E-13
2400 1.30E-13
2500 1.16E-13