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Title: Kinetics and mechanisms of the self-reactions of CCl3O2 and CHCl2O2 radicals and their reactions with HO2
Journal: J. Phys. Chem.
Volume: 100
Page(s): 14356 - 14371
Year: 1996
Reference type: Journal article
Squib: 1996CAT/LES14356-14371
Reaction:
CHCl3 + ·F → ·CCl3 + HF
Reaction order:
2
Reference reaction:
CH4 + ·F → ·CH3 + HF
Temperature:
298
K
Pressure: 0.93 bar
Rate expression:
5.4x10-12 [±1.51x10-12 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Vis-UV absorption
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