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Author(s):   Catoire, V.; Lesclaux, R.; Schneider, W.F.; Wallington, T.J.
Title:   Kinetics and mechanisms of the self-reactions of CCl3O2 and CHCl2O2 radicals and their reactions with HO2
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   14356 - 14371
Year:   1996
Reference type:   Journal article
Squib:   1996CAT/LES14356-14371

Reaction:   CH2Cl2 + ClCHCl2 + HCl
Reaction order:   2
Reference reaction:   CH4 + Cl·CH3 + HCl
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   3.5x10-13 [±3.82x10-14 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

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