NIST Chemical Kinetics Database

Author(s):   Czarnowski, I.
Title:   Kinetics and mechanism of the thermal gas-phase reaction between trifluoromethylhypofluorite, CF₃OF, and tetrachloroethene
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   489 - 495
Year:   1996
Reference type:   Journal article
Squib:   1996CZA489-495

Reaction:   C₂Cl₄ + CF₃OF → ·CCl₂CFCl₂ + CF₃O
Reaction order:   2
Temperature:   313 - 343 K
Pressure:  2.21E-2 - 0.12 bar
Rate expression:   5.25x10^-14 [±9.96x10^-15 cm³/molecule s] e^{-63606 [±7001 J/mole]/RT}
Bath gas:   N2
Category: Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [cm³/molecule s]
313	1.27E-24
325	3.14E-24
343	1.08E-23