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Title: Experimental and estimated rate constants for the reactions of hydroxyl radicals with several halocarbons
Journal: J. Phys. Chem.
Volume: 100
Page(s): 5813 - 5820
Year: 1996
Reference type: Journal article
Squib: 1996DEM5813-5820
Reaction:
CH3F + ·OH → ·CH2F + H2O
Reaction order:
2
Reference reaction:
CH3Cl + ·OH → ·CH2Cl + H2O
Temperature:
308 - 398
K
Pressure: 1.01 bar
Rate expression:
4.4x10-12 [cm3/molecule s] e-13802 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 308 | 2.01E-14 |
| 325 | 2.66E-14 |
| 350 | 3.83E-14 |
| 375 | 5.26E-14 |
| 398 | 6.79E-14 |