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Author(s):   Dianxun, W.; Ximei, Q.; Peng, J.
Title:   A novel method for the kinetic study of a chemical reaction. Determination of the kinetic parameters of the isomerisation reaction of methyl isocyanide using HeI photoelectron spectroscopy
Journal:   Chem. Phys. Lett.
Volume:   258
Page(s):   149 - 154
Year:   1996
Reference type:   Journal article
Squib:   1996DIA/XIM149-154

Reaction:   CH3NCCH3CN
Reaction order:   1
Temperature:   483 - 503 K
Pressure:  1.01 bar
Rate expression:   4.79x1013 [s-1] e-161301 [J/mole]/RT
Bath gas:   CH3NC
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (Vis-UV)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
483 1.72E-4
500 6.76E-4
503 8.52E-4