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Title: A novel method for the kinetic study of a chemical reaction. Determination of the kinetic parameters of the isomerisation reaction of methyl isocyanide using HeI photoelectron spectroscopy
Journal: Chem. Phys. Lett.
Volume: 258
Page(s): 149 - 154
Year: 1996
Reference type: Journal article
Squib: 1996DIA/XIM149-154
Reaction:
CH3NC → CH3CN
Reaction order:
1
Temperature:
483 - 503
K
Pressure: 1.01 bar
Rate expression:
4.79x1013 [s-1] e-161301 [J/mole]/RT
Bath gas:
CH3NC
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (Vis-UV)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 483 | 1.72E-4 |
| 500 | 6.76E-4 |
| 503 | 8.52E-4 |