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Title: Direct kinetic studies of the reactions Br + CH3OH and CH2OH + HBr: the heat of formation of CH2OH
Journal: J. Phys. Chem.
Volume: 100
Page(s): 19864 - 19873
Year: 1996
Reference type: Journal article
Squib: 1996DOB/BER19864-19873
Reaction:
CH3OH + Br· → (·)CH2OH + HBr
Reaction order:
2
Temperature:
439 - 713
K
Pressure: 0.17 bar
Rate expression:
2.91x10-11 [±7.64x10-12 cm3/molecule s] (T/298 K)1.50 e-29932 [±1497 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 439 | 1.43E-14 |
| 450 | 1.81E-14 |
| 475 | 2.99E-14 |
| 500 | 4.72E-14 |
| 525 | 7.15E-14 |
| 550 | 1.05E-13 |
| 575 | 1.49E-13 |
| 600 | 2.06E-13 |
| 625 | 2.78E-13 |
| 650 | 3.68E-13 |
| 675 | 4.78E-13 |
| 700 | 6.11E-13 |
| 713 | 6.90E-13 |