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Author(s):   El Boudali, A.; Le Calve, S.; Le Bras, G.; Mellouki, A.
Title:   Kinetic studies of OH reactions with a series of acetates
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   12364 - 12368
Year:   1996
Reference type:   Journal article
Squib:   1996ELB/LEC12364-12368

Reaction:   CH3COOC2H5 + ·OH → Products
Reaction order:   2
Temperature:   243 - 369 K
Pressure:  1.13 bar
Rate expression:   4.8x10-13 [±9.13x10-14 cm3/molecule s] e3301 [±856 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
243 2.46E-12
250 2.35E-12
275 2.03E-12
300 1.80E-12
325 1.63E-12
350 1.49E-12
369 1.41E-12