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Title: The reaction of phenoxy radicals with mono-chlorobenzene and its meaning for gas-phase dioxin formation in incineration
Journal: Symp. Int. Combust. Proc.
Volume: 26
Page(s): 2405 - 2411
Year: 1996
Reference type: Journal article
Squib: 1996GRO/LOU2405-2411
Reaction:
Chlorobenzene + C6H5O → Diphenyl ether + Cl
Reaction order:
2
Temperature:
728 - 984
K
Pressure: 1.01 bar
Rate expression:
7.97x10-13 [cm3/molecule s] e-102268 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Time resolution:
In both real time and by end product analysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 728 | 3.66E-20 |
| 750 | 6.01E-20 |
| 775 | 1.02E-19 |
| 800 | 1.68E-19 |
| 825 | 2.67E-19 |
| 850 | 4.14E-19 |
| 875 | 6.26E-19 |
| 900 | 9.25E-19 |
| 925 | 1.34E-18 |
| 950 | 1.90E-18 |
| 975 | 2.65E-18 |
| 984 | 2.97E-18 |