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Author(s):   Huybrechts, G.; Narmon, M.; Van Mele, B.
Title:   The pyrolysis of CCl4 and C2Cl6 in the gas phase. Mechanistic modeling by thermodynamic and kinetic parameter estimation
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   27 - 36
Year:   1996
Reference type:   Journal article
Squib:   1996HUY/NAR27-36

Reaction:   CCl3CCl3 + ·CCl3 → CCl4 + C2Cl5
Reaction order:   2
Temperature:   300 - 800 K
Rate expression:   1.35x10-12 [cm3/molecule s] e-59033 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 7.11E-23
350 2.09E-21
400 2.64E-20
450 1.90E-19
500 9.19E-19
550 3.34E-18
600 9.80E-18
650 2.44E-17
700 5.31E-17
750 1.04E-16
800 1.89E-16