Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Ikeda, E.; Mackie, J.C.
Title:   A kinetic study of the oxidaiton of acetonitrile: a model for NO formation from fuel-bound nitrogen
Journal:   Symp. Int. Combust. Proc.
Volume:   26
Page(s):   597 - 604
Year:   1996
Reference type:   Journal article
Squib:   1996IKE/MAC597-604

Reaction:   CH3CNCH2CN +
Reaction order:   1
Temperature:   1300 - 2100 K
Pressure:  11.00 - 20.00 bar
Rate expression:   1.0x1016 [s-1] e-402420 [±8048 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 6.77E-1
1350 2.69E0
1400 9.68E0
1450 3.19E1
1500 9.70E1
1550 2.75E2
1600 7.29E2
1650 1.82E3
1700 4.32E3
1750 9.74E3
1800 2.10E4
1850 4.34E4
1900 8.65E4
1950 1.66E5
2000 3.09E5
2050 5.58E5
2100 9.78E5