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Author(s):   Kumaran, S.S.; Su, M.-C.; Lim, K.P.; Michael, J.V.; Wagner, A.F.; Harding, L.B.
Title:   Ab initio calculations and three different applications of unimolecular rate theory for the dissociations of CCl4, CFCl3, CF2Cl2, and CF3Cl
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   7541 - 7549
Year:   1996
Reference type:   Journal article
Squib:   1996KUM/SU7541-7549

Reaction:   CCl4·CCl3 + Cl
Reaction order:   1
Temperature:   1050 - 2200 K
Rate expression:   1.11x1017 [s-1] (T/298 K)-1.30 e-288737 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 9.37E1
1100 3.97E2
1200 4.92E3
1300 4.11E4
1400 2.51E5
1500 1.20E6
1600 4.69E6
1700 1.56E7
1800 4.49E7
1900 1.16E8
2000 2.70E8
2100 5.79E8
2200 1.15E9